1 Ocak 2014 Dergi makalesi Açık Erişim

Tarakci, Deniz Kutlu; Gurol, Ilke

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  <dc:creator>Tarakci, Deniz Kutlu</dc:creator>
  <dc:creator>Gurol, Ilke</dc:creator>
  <dc:date>2014-01-01</dc:date>
  <dc:description>In this paper, the synthesis and characterization of peripheral tetra-2-(2-ethyloxyethyloxy)ethyloxy substituted oxo-titanium phthalocyanines (TiOPcs) are reported. The reaction of 2,2,3,3-tetrafluoropropoxy substituted and [2-(2-ethoxyethoxy) ethoxy] substituted TiOPcs (1 and 3) with 4-[(6-hydroxyhexyl)oxy]benzene-1,2-diol as a strongly chelating oxygen donor ligand is described. Compounds 1 a and 3 a bearing the hydroxyl group as an axial ligand of the bulky group are converted into a thiol group (1c and 3c). The new compounds are characterized by elemental analysis, FT-IR, (1) H NMR, and mass spectrometry. While the fluoropropoxy substituted TiOPc has good solubility in polar solvents such as acetone and THF, the other TiOPc is soluble in chloroform.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/90519</dc:identifier>
  <dc:identifier>oai:zenodo.org:90519</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>TURKISH JOURNAL OF CHEMISTRY 38(6) 1056-1063</dc:source>
  <dc:title>Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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