1 Ocak 2014 Dergi makalesi Açık Erişim

Tarakci, Deniz Kutlu; Gurol, Ilke

Citation Style Language JSON

{
  "DOI": "10.3906/kim-1406-46", 
  "abstract": "In this paper, the synthesis and characterization of peripheral tetra-2-(2-ethyloxyethyloxy)ethyloxy substituted oxo-titanium phthalocyanines (TiOPcs) are reported. The reaction of 2,2,3,3-tetrafluoropropoxy substituted and [2-(2-ethoxyethoxy) ethoxy] substituted TiOPcs (1 and 3) with 4-[(6-hydroxyhexyl)oxy]benzene-1,2-diol as a strongly chelating oxygen donor ligand is described. Compounds 1 a and 3 a bearing the hydroxyl group as an axial ligand of the bulky group are converted into a thiol group (1c and 3c). The new compounds are characterized by elemental analysis, FT-IR, (1) H NMR, and mass spectrometry. While the fluoropropoxy substituted TiOPc has good solubility in polar solvents such as acetone and THF, the other TiOPc is soluble in chloroform.", 
  "author": [
    {
      "family": "Tarakci", 
      "given": " Deniz Kutlu"
    }, 
    {
      "family": "Gurol", 
      "given": " Ilke"
    }
  ], 
  "container_title": "TURKISH JOURNAL OF CHEMISTRY", 
  "id": "90519", 
  "issue": "6", 
  "issued": {
    "date-parts": [
      [
        2014, 
        1, 
        1
      ]
    ]
  }, 
  "page": "1056-1063", 
  "title": "Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand", 
  "type": "article-journal", 
  "volume": "38"
}