1 Ocak 2014 Dergi makalesi Açık Erişim

Tarakci, Deniz Kutlu; Gurol, Ilke

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/90519</identifier>
  <creators>
    <creator>
      <creatorName>Tarakci, Deniz Kutlu</creatorName>
      <givenName>Deniz Kutlu</givenName>
      <familyName>Tarakci</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gurol, Ilke</creatorName>
      <givenName>Ilke</givenName>
      <familyName>Gurol</familyName>
      <affiliation>Tubitak Marmara Res Ctr, Mat Inst, Gebze, Kocaeli, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Characterization Of Tetra-Substituted Titanium(Iv) Phthalocyanines With Axial Ligand</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2014</publicationYear>
  <dates>
    <date dateType="Issued">2014-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/90519</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.3906/kim-1406-46</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this paper, the synthesis and characterization of peripheral tetra-2-(2-ethyloxyethyloxy)ethyloxy substituted oxo-titanium phthalocyanines (TiOPcs) are reported. The reaction of 2,2,3,3-tetrafluoropropoxy substituted and [2-(2-ethoxyethoxy) ethoxy] substituted TiOPcs (1 and 3) with 4-[(6-hydroxyhexyl)oxy]benzene-1,2-diol as a strongly chelating oxygen donor ligand is described. Compounds 1 a and 3 a bearing the hydroxyl group as an axial ligand of the bulky group are converted into a thiol group (1c and 3c). The new compounds are characterized by elemental analysis, FT-IR, (1) H NMR, and mass spectrometry. While the fluoropropoxy substituted TiOPc has good solubility in polar solvents such as acetone and THF, the other TiOPc is soluble in chloroform.</description>
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