1 Ocak 2014 Dergi makalesi Açık Erişim

Tarakci, Deniz Kutlu; Gurol, Ilke

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{
  "@context": "https://schema.org/", 
  "@id": 90519, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
      "name": "Tarakci, Deniz Kutlu"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Tubitak Marmara Res Ctr, Mat Inst, Gebze, Kocaeli, Turkey", 
      "name": "Gurol, Ilke"
    }
  ], 
  "datePublished": "2014-01-01", 
  "description": "In this paper, the synthesis and characterization of peripheral tetra-2-(2-ethyloxyethyloxy)ethyloxy substituted oxo-titanium phthalocyanines (TiOPcs) are reported. The reaction of 2,2,3,3-tetrafluoropropoxy substituted and [2-(2-ethoxyethoxy) ethoxy] substituted TiOPcs (1 and 3) with 4-[(6-hydroxyhexyl)oxy]benzene-1,2-diol as a strongly chelating oxygen donor ligand is described. Compounds 1 a and 3 a bearing the hydroxyl group as an axial ligand of the bulky group are converted into a thiol group (1c and 3c). The new compounds are characterized by elemental analysis, FT-IR, (1) H NMR, and mass spectrometry. While the fluoropropoxy substituted TiOPc has good solubility in polar solvents such as acetone and THF, the other TiOPc is soluble in chloroform.", 
  "headline": "Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand", 
  "identifier": 90519, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand", 
  "url": "https://aperta.ulakbim.gov.tr/record/90519"
}