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Synthesis and characterization of tetra-substituted titanium(IV) phthalocyanines with axial ligand

Tarakci, Deniz Kutlu; Gurol, Ilke


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        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey", 
        "name": "Tarakci, Deniz Kutlu"
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        "affiliation": "Tubitak Marmara Res Ctr, Mat Inst, Gebze, Kocaeli, Turkey", 
        "name": "Gurol, Ilke"
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    "description": "In this paper, the synthesis and characterization of peripheral tetra-2-(2-ethyloxyethyloxy)ethyloxy substituted oxo-titanium phthalocyanines (TiOPcs) are reported. The reaction of 2,2,3,3-tetrafluoropropoxy substituted and [2-(2-ethoxyethoxy) ethoxy] substituted TiOPcs (1 and 3) with 4-[(6-hydroxyhexyl)oxy]benzene-1,2-diol as a strongly chelating oxygen donor ligand is described. Compounds 1 a and 3 a bearing the hydroxyl group as an axial ligand of the bulky group are converted into a thiol group (1c and 3c). The new compounds are characterized by elemental analysis, FT-IR, (1) H NMR, and mass spectrometry. While the fluoropropoxy substituted TiOPc has good solubility in polar solvents such as acetone and THF, the other TiOPc is soluble in chloroform.", 
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      "issue": "6", 
      "pages": "1056-1063", 
      "title": "TURKISH JOURNAL OF CHEMISTRY", 
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