1 Ocak 2019 Dergi makalesi Açık Erişim

Ozcan, Emrah; Tumay, Sureyya Oguz; Kesan, Gurkan; Yesilot, Serkan; Cosut, Bunyemin

Dublin Core

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  <dc:creator>Ozcan, Emrah</dc:creator>
  <dc:creator>Tumay, Sureyya Oguz</dc:creator>
  <dc:creator>Kesan, Gurkan</dc:creator>
  <dc:creator>Yesilot, Serkan</dc:creator>
  <dc:creator>Cosut, Bunyemin</dc:creator>
  <dc:date>2019-01-01</dc:date>
  <dc:description>Novel fluorescent anthracene-decorated cyclotri- and cyclotetraphosphazenes (5 and 6) are designed and synthesized, and their chemosensor behaviors against nitroaromatic compounds are examined by UV/Vis and fluorescence spectroscopies for addressing the sensors with cyclophosphazenes for 2,4,6-trinitrotoluene detection. The fluorescence intensities of (5 and 6) are found to be selectively quenched by only 2,4,6-trinitrotoluene through the non-covalent pi center dot center dot center dot pi stacking interactions between anthracene-substituted cyclophosphazenes and 2,4,6-trinitrotoluene. In addition, cyclic voltammetry and theoretical calculation of novel sensor systems are studied. The proposed fluorescent sensor systems are critical in terms of practical detection of 2,4,6-trinitrotoluene. (C) 2019 Elsevier B.V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/70295</dc:identifier>
  <dc:identifier>oai:zenodo.org:70295</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 220</dc:source>
  <dc:title>The novel anthracene decorated dendrimeric cyclophosphazenes for highly selective sensing of 2,4,6-trinitrotoluene (TNT)</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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