1 Ocak 2019 Dergi makalesi Açık Erişim

Ozcan, Emrah; Tumay, Sureyya Oguz; Kesan, Gurkan; Yesilot, Serkan; Cosut, Bunyemin

Citation Style Language JSON

{
  "DOI": "10.1016/j.saa.2019.05.020", 
  "abstract": "Novel fluorescent anthracene-decorated cyclotri- and cyclotetraphosphazenes (5 and 6) are designed and synthesized, and their chemosensor behaviors against nitroaromatic compounds are examined by UV/Vis and fluorescence spectroscopies for addressing the sensors with cyclophosphazenes for 2,4,6-trinitrotoluene detection. The fluorescence intensities of (5 and 6) are found to be selectively quenched by only 2,4,6-trinitrotoluene through the non-covalent pi center dot center dot center dot pi stacking interactions between anthracene-substituted cyclophosphazenes and 2,4,6-trinitrotoluene. In addition, cyclic voltammetry and theoretical calculation of novel sensor systems are studied. The proposed fluorescent sensor systems are critical in terms of practical detection of 2,4,6-trinitrotoluene. (C) 2019 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Ozcan", 
      "given": " Emrah"
    }, 
    {
      "family": "Tumay", 
      "given": " Sureyya Oguz"
    }, 
    {
      "family": "Kesan", 
      "given": " Gurkan"
    }, 
    {
      "family": "Yesilot", 
      "given": " Serkan"
    }, 
    {
      "family": "Cosut", 
      "given": " Bunyemin"
    }
  ], 
  "container_title": "SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY", 
  "id": "70295", 
  "issued": {
    "date-parts": [
      [
        2019, 
        1, 
        1
      ]
    ]
  }, 
  "title": "The novel anthracene decorated dendrimeric cyclophosphazenes for highly selective sensing of 2,4,6-trinitrotoluene (TNT)", 
  "type": "article-journal", 
  "volume": "220"
}