1 Ocak 2019 Dergi makalesi Açık Erişim

Ozcan, Emrah; Tumay, Sureyya Oguz; Kesan, Gurkan; Yesilot, Serkan; Cosut, Bunyemin

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/70295</identifier>
  <creators>
    <creator>
      <creatorName>Ozcan, Emrah</creatorName>
      <givenName>Emrah</givenName>
      <familyName>Ozcan</familyName>
      <affiliation>Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tumay, Sureyya Oguz</creatorName>
      <givenName>Sureyya Oguz</givenName>
      <familyName>Tumay</familyName>
      <affiliation>Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kesan, Gurkan</creatorName>
      <givenName>Gurkan</givenName>
      <familyName>Kesan</familyName>
      <affiliation>Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yesilot, Serkan</creatorName>
      <givenName>Serkan</givenName>
      <familyName>Yesilot</familyName>
      <affiliation>Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Cosut, Bunyemin</creatorName>
      <givenName>Bunyemin</givenName>
      <familyName>Cosut</familyName>
      <affiliation>Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>The Novel Anthracene Decorated Dendrimeric Cyclophosphazenes For Highly Selective Sensing Of 2,4,6-Trinitrotoluene (Tnt)</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2019</publicationYear>
  <dates>
    <date dateType="Issued">2019-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/70295</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.saa.2019.05.020</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Novel fluorescent anthracene-decorated cyclotri- and cyclotetraphosphazenes (5 and 6) are designed and synthesized, and their chemosensor behaviors against nitroaromatic compounds are examined by UV/Vis and fluorescence spectroscopies for addressing the sensors with cyclophosphazenes for 2,4,6-trinitrotoluene detection. The fluorescence intensities of (5 and 6) are found to be selectively quenched by only 2,4,6-trinitrotoluene through the non-covalent pi center dot center dot center dot pi stacking interactions between anthracene-substituted cyclophosphazenes and 2,4,6-trinitrotoluene. In addition, cyclic voltammetry and theoretical calculation of novel sensor systems are studied. The proposed fluorescent sensor systems are critical in terms of practical detection of 2,4,6-trinitrotoluene. (C) 2019 Elsevier B.V. All rights reserved.</description>
  </descriptions>
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