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The novel anthracene decorated dendrimeric cyclophosphazenes for highly selective sensing of 2,4,6-trinitrotoluene (TNT)

Ozcan, Emrah; Tumay, Sureyya Oguz; Kesan, Gurkan; Yesilot, Serkan; Cosut, Bunyemin


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        "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
        "name": "Ozcan, Emrah"
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      {
        "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
        "name": "Tumay, Sureyya Oguz"
      }, 
      {
        "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
        "name": "Kesan, Gurkan"
      }, 
      {
        "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
        "name": "Yesilot, Serkan"
      }, 
      {
        "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
        "name": "Cosut, Bunyemin"
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    "description": "Novel fluorescent anthracene-decorated cyclotri- and cyclotetraphosphazenes (5 and 6) are designed and synthesized, and their chemosensor behaviors against nitroaromatic compounds are examined by UV/Vis and fluorescence spectroscopies for addressing the sensors with cyclophosphazenes for 2,4,6-trinitrotoluene detection. The fluorescence intensities of (5 and 6) are found to be selectively quenched by only 2,4,6-trinitrotoluene through the non-covalent pi center dot center dot center dot pi stacking interactions between anthracene-substituted cyclophosphazenes and 2,4,6-trinitrotoluene. In addition, cyclic voltammetry and theoretical calculation of novel sensor systems are studied. The proposed fluorescent sensor systems are critical in terms of practical detection of 2,4,6-trinitrotoluene. (C) 2019 Elsevier B.V. All rights reserved.", 
    "doi": "10.1016/j.saa.2019.05.020", 
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      "title": "SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY", 
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