1 Ocak 2019 Dergi makalesi Açık Erişim

Ozcan, Emrah; Tumay, Sureyya Oguz; Kesan, Gurkan; Yesilot, Serkan; Cosut, Bunyemin

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  "@id": 70295, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
      "name": "Ozcan, Emrah"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
      "name": "Tumay, Sureyya Oguz"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
      "name": "Kesan, Gurkan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
      "name": "Yesilot, Serkan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey", 
      "name": "Cosut, Bunyemin"
    }
  ], 
  "datePublished": "2019-01-01", 
  "description": "Novel fluorescent anthracene-decorated cyclotri- and cyclotetraphosphazenes (5 and 6) are designed and synthesized, and their chemosensor behaviors against nitroaromatic compounds are examined by UV/Vis and fluorescence spectroscopies for addressing the sensors with cyclophosphazenes for 2,4,6-trinitrotoluene detection. The fluorescence intensities of (5 and 6) are found to be selectively quenched by only 2,4,6-trinitrotoluene through the non-covalent pi center dot center dot center dot pi stacking interactions between anthracene-substituted cyclophosphazenes and 2,4,6-trinitrotoluene. In addition, cyclic voltammetry and theoretical calculation of novel sensor systems are studied. The proposed fluorescent sensor systems are critical in terms of practical detection of 2,4,6-trinitrotoluene. (C) 2019 Elsevier B.V. All rights reserved.", 
  "headline": "The novel anthracene decorated dendrimeric cyclophosphazenes for highly selective sensing of 2,4,6-trinitrotoluene (TNT)", 
  "identifier": 70295, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "The novel anthracene decorated dendrimeric cyclophosphazenes for highly selective sensing of 2,4,6-trinitrotoluene (TNT)", 
  "url": "https://aperta.ulakbim.gov.tr/record/70295"
}