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Coburger, Peter; Kahraman, Gizem; Straube, Axel; Hey-Hawkins, Evamarie
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"> <dc:creator>Coburger, Peter</dc:creator> <dc:creator>Kahraman, Gizem</dc:creator> <dc:creator>Straube, Axel</dc:creator> <dc:creator>Hey-Hawkins, Evamarie</dc:creator> <dc:date>2019-01-01</dc:date> <dc:description>Two distorted square-planar Rh-I complexes (1 and 2) were obtained from [{RhCl(eta(4)-cod)}(2)] and the respective P,N ligands. The metal-ligand interaction was probed with density functional theory (DFT) and ab initio (CASSCF-NEVPT2) calculations. NMR spectroscopy proved dynamic binding behaviour of the ligands in solution. The tetradenticity of the ligands also affects the electrochemical behaviour of complexes 1 and 2 significantly. Finally, preliminary catalytic studies, namely the dehydrocoupling of dimethylamine-borane, are presented.</dc:description> <dc:identifier>https://aperta.ulakbim.gov.trrecord/69587</dc:identifier> <dc:identifier>oai:zenodo.org:69587</dc:identifier> <dc:rights>info:eu-repo/semantics/openAccess</dc:rights> <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights> <dc:source>DALTON TRANSACTIONS 48(26) 9625-9630</dc:source> <dc:title>Rhodium(i) complexes with carborane-substituted P,N ligands: investigations of electronic structure and dynamic behaviour</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> <dc:type>publication-article</dc:type> </oai_dc:dc>
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