1 Ocak 2019 Dergi makalesi Açık Erişim

Coburger, Peter; Kahraman, Gizem; Straube, Axel; Hey-Hawkins, Evamarie

Dublin Core

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  <dc:creator>Coburger, Peter</dc:creator>
  <dc:creator>Kahraman, Gizem</dc:creator>
  <dc:creator>Straube, Axel</dc:creator>
  <dc:creator>Hey-Hawkins, Evamarie</dc:creator>
  <dc:date>2019-01-01</dc:date>
  <dc:description>Two distorted square-planar Rh-I complexes (1 and 2) were obtained from [{RhCl(eta(4)-cod)}(2)] and the respective P,N ligands. The metal-ligand interaction was probed with density functional theory (DFT) and ab initio (CASSCF-NEVPT2) calculations. NMR spectroscopy proved dynamic binding behaviour of the ligands in solution. The tetradenticity of the ligands also affects the electrochemical behaviour of complexes 1 and 2 significantly. Finally, preliminary catalytic studies, namely the dehydrocoupling of dimethylamine-borane, are presented.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/69587</dc:identifier>
  <dc:identifier>oai:zenodo.org:69587</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>DALTON TRANSACTIONS 48(26) 9625-9630</dc:source>
  <dc:title>Rhodium(i) complexes with carborane-substituted P,N ligands: investigations of electronic structure and dynamic behaviour</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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