1 Ocak 2019 Dergi makalesi Açık Erişim

Coburger, Peter; Kahraman, Gizem; Straube, Axel; Hey-Hawkins, Evamarie

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        "affiliation": "Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany", 
        "name": "Coburger, Peter"
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      {
        "name": "Kahraman, Gizem"
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        "affiliation": "Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany", 
        "name": "Straube, Axel"
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      {
        "affiliation": "Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany", 
        "name": "Hey-Hawkins, Evamarie"
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    "description": "Two distorted square-planar Rh-I complexes (1 and 2) were obtained from [{RhCl(eta(4)-cod)}(2)] and the respective P,N ligands. The metal-ligand interaction was probed with density functional theory (DFT) and ab initio (CASSCF-NEVPT2) calculations. NMR spectroscopy proved dynamic binding behaviour of the ligands in solution. The tetradenticity of the ligands also affects the electrochemical behaviour of complexes 1 and 2 significantly. Finally, preliminary catalytic studies, namely the dehydrocoupling of dimethylamine-borane, are presented.", 
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    "journal": {
      "issue": "26", 
      "pages": "9625-9630", 
      "title": "DALTON TRANSACTIONS", 
      "volume": "48"
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    "publication_date": "2019-01-01", 
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    "title": "Rhodium(i) complexes with carborane-substituted P,N ligands: investigations of electronic structure and dynamic behaviour"
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