1 Ocak 2019 Dergi makalesi Açık Erişim

Coburger, Peter; Kahraman, Gizem; Straube, Axel; Hey-Hawkins, Evamarie

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{
  "@context": "https://schema.org/", 
  "@id": 69587, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany", 
      "name": "Coburger, Peter"
    }, 
    {
      "@type": "Person", 
      "name": "Kahraman, Gizem"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany", 
      "name": "Straube, Axel"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany", 
      "name": "Hey-Hawkins, Evamarie"
    }
  ], 
  "datePublished": "2019-01-01", 
  "description": "Two distorted square-planar Rh-I complexes (1 and 2) were obtained from [{RhCl(eta(4)-cod)}(2)] and the respective P,N ligands. The metal-ligand interaction was probed with density functional theory (DFT) and ab initio (CASSCF-NEVPT2) calculations. NMR spectroscopy proved dynamic binding behaviour of the ligands in solution. The tetradenticity of the ligands also affects the electrochemical behaviour of complexes 1 and 2 significantly. Finally, preliminary catalytic studies, namely the dehydrocoupling of dimethylamine-borane, are presented.", 
  "headline": "Rhodium(i) complexes with carborane-substituted P,N ligands: investigations of electronic structure and dynamic behaviour", 
  "identifier": 69587, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Rhodium(i) complexes with carborane-substituted P,N ligands: investigations of electronic structure and dynamic behaviour", 
  "url": "https://aperta.ulakbim.gov.tr/record/69587"
}