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Coburger, Peter; Kahraman, Gizem; Straube, Axel; Hey-Hawkins, Evamarie
{ "DOI": "10.1039/c9dt00628a", "abstract": "Two distorted square-planar Rh-I complexes (1 and 2) were obtained from [{RhCl(eta(4)-cod)}(2)] and the respective P,N ligands. The metal-ligand interaction was probed with density functional theory (DFT) and ab initio (CASSCF-NEVPT2) calculations. NMR spectroscopy proved dynamic binding behaviour of the ligands in solution. The tetradenticity of the ligands also affects the electrochemical behaviour of complexes 1 and 2 significantly. Finally, preliminary catalytic studies, namely the dehydrocoupling of dimethylamine-borane, are presented.", "author": [ { "family": "Coburger", "given": " Peter" }, { "family": "Kahraman", "given": " Gizem" }, { "family": "Straube", "given": " Axel" }, { "family": "Hey-Hawkins", "given": " Evamarie" } ], "container_title": "DALTON TRANSACTIONS", "id": "69587", "issue": "26", "issued": { "date-parts": [ [ 2019, 1, 1 ] ] }, "page": "9625-9630", "title": "Rhodium(i) complexes with carborane-substituted P,N ligands: investigations of electronic structure and dynamic behaviour", "type": "article-journal", "volume": "48" }
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