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L-proline derivatives based on a calix[4]arene scaffold as chiral organocatalysts for the direct asymmetric aldol reaction in water

Aktas, Mehmet; Uyanik, Arzu; Eymur, Serkan; Yilmaz, Mustafa


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{
  "@context": "https://schema.org/", 
  "@id": 58845, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Selcuk Univ, Dept Chem, Konya, Turkey", 
      "name": "Aktas, Mehmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Selcuk Univ, Dept Chem, Konya, Turkey", 
      "name": "Uyanik, Arzu"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Giresun Univ, Dept Energy Syst Engn, Giresun, Turkey", 
      "name": "Eymur, Serkan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Selcuk Univ, Dept Chem, Konya, Turkey", 
      "name": "Yilmaz, Mustafa"
    }
  ], 
  "datePublished": "2016-01-01", 
  "description": "A new series of water-compatible proline catalysts (4-6) derived from calixarene bearing a hydrophobic nature have been synthesised. It was found that the compound 4 was a highly efficient organocatalyst for aldol reactions occurred in the water. Under optimised reaction conditions, high yields (up to 82%), good enantioselectivities (ee up to 81%) and high diastereoselectivities (dr up to 91:9) were obtained.", 
  "headline": "L-proline derivatives based on a calix[4]arene scaffold as chiral organocatalysts for the direct asymmetric aldol reaction in water", 
  "identifier": 58845, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "L-proline derivatives based on a calix[4]arene scaffold as chiral organocatalysts for the direct asymmetric aldol reaction in water", 
  "url": "https://aperta.ulakbim.gov.tr/record/58845"
}
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