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Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction

Yilmaz, Mustafa Kemal; Keles, Huelya; Ince, Simay; Keles, Mustafa


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  <dc:creator>Yilmaz, Mustafa Kemal</dc:creator>
  <dc:creator>Keles, Huelya</dc:creator>
  <dc:creator>Ince, Simay</dc:creator>
  <dc:creator>Keles, Mustafa</dc:creator>
  <dc:date>2018-01-01</dc:date>
  <dc:description>Three iminophosphine ligands having soft phosphorus and hard nitrogen atoms and their Pd(II) complexes were synthesized and characterized using H-1 NMR, C-13 NMR, P-31 NMR and Fourier transform infrared spectroscopic techniques. Also, electrochemical properties of the iminophosphines and their Pd(II) complexes were investigated in acetonitrile-tetrabutylammonium perchlorate solution with cyclic and square wave voltammetry techniques. All Pd(II) complexes were evaluated as catalysts for carbonylative cross-coupling reactions of aryl iodides with phenylboronic acid. The Suzuki carbonylation of aryl iodides at 80 degrees C under balloon pressure of carbon monoxide in the presence of K2CO3 as a base was examined, and good to high conversions and excellent selectivities were obtained.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/33829</dc:identifier>
  <dc:identifier>oai:zenodo.org:33829</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>APPLIED ORGANOMETALLIC CHEMISTRY 32(2)</dc:source>
  <dc:title>Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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