Dergi makalesi Açık Erişim
Yilmaz, Mustafa Kemal; Keles, Huelya; Ince, Simay; Keles, Mustafa
{ "DOI": "10.1002/aoc.4002", "abstract": "Three iminophosphine ligands having soft phosphorus and hard nitrogen atoms and their Pd(II) complexes were synthesized and characterized using H-1 NMR, C-13 NMR, P-31 NMR and Fourier transform infrared spectroscopic techniques. Also, electrochemical properties of the iminophosphines and their Pd(II) complexes were investigated in acetonitrile-tetrabutylammonium perchlorate solution with cyclic and square wave voltammetry techniques. All Pd(II) complexes were evaluated as catalysts for carbonylative cross-coupling reactions of aryl iodides with phenylboronic acid. The Suzuki carbonylation of aryl iodides at 80 degrees C under balloon pressure of carbon monoxide in the presence of K2CO3 as a base was examined, and good to high conversions and excellent selectivities were obtained.", "author": [ { "family": "Yilmaz", "given": " Mustafa Kemal" }, { "family": "Keles", "given": " Huelya" }, { "family": "Ince", "given": " Simay" }, { "family": "Keles", "given": " Mustafa" } ], "container_title": "APPLIED ORGANOMETALLIC CHEMISTRY", "id": "33829", "issue": "2", "issued": { "date-parts": [ [ 2018, 1, 1 ] ] }, "title": "Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction", "type": "article-journal", "volume": "32" }
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