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Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction

Yilmaz, Mustafa Kemal; Keles, Huelya; Ince, Simay; Keles, Mustafa


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{
  "DOI": "10.1002/aoc.4002", 
  "abstract": "Three iminophosphine ligands having soft phosphorus and hard nitrogen atoms and their Pd(II) complexes were synthesized and characterized using H-1 NMR, C-13 NMR, P-31 NMR and Fourier transform infrared spectroscopic techniques. Also, electrochemical properties of the iminophosphines and their Pd(II) complexes were investigated in acetonitrile-tetrabutylammonium perchlorate solution with cyclic and square wave voltammetry techniques. All Pd(II) complexes were evaluated as catalysts for carbonylative cross-coupling reactions of aryl iodides with phenylboronic acid. The Suzuki carbonylation of aryl iodides at 80 degrees C under balloon pressure of carbon monoxide in the presence of K2CO3 as a base was examined, and good to high conversions and excellent selectivities were obtained.", 
  "author": [
    {
      "family": "Yilmaz", 
      "given": " Mustafa Kemal"
    }, 
    {
      "family": "Keles", 
      "given": " Huelya"
    }, 
    {
      "family": "Ince", 
      "given": " Simay"
    }, 
    {
      "family": "Keles", 
      "given": " Mustafa"
    }
  ], 
  "container_title": "APPLIED ORGANOMETALLIC CHEMISTRY", 
  "id": "33829", 
  "issue": "2", 
  "issued": {
    "date-parts": [
      [
        2018, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction", 
  "type": "article-journal", 
  "volume": "32"
}
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