1 Ocak 2018 Dergi makalesi Açık Erişim

Yilmaz, Mustafa Kemal; Keles, Huelya; Ince, Simay; Keles, Mustafa

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/33829</identifier>
  <creators>
    <creator>
      <creatorName>Yilmaz, Mustafa Kemal</creatorName>
      <givenName>Mustafa Kemal</givenName>
      <familyName>Yilmaz</familyName>
      <affiliation>Mersin Univ, Fac Arts &amp; Sci, Dept Chem, TR-33343 Mersin, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Keles, Huelya</creatorName>
      <givenName>Huelya</givenName>
      <familyName>Keles</familyName>
      <affiliation>Osmaniye Korkut Ata Univ, Fac Arts &amp; Sci, Dept Chem, TR-80000 Osmaniye, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ince, Simay</creatorName>
      <givenName>Simay</givenName>
      <familyName>Ince</familyName>
      <affiliation>Osmaniye Korkut Ata Univ, Fac Arts &amp; Sci, Dept Chem, TR-80000 Osmaniye, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Keles, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Keles</familyName>
      <affiliation>Osmaniye Korkut Ata Univ, Fac Arts &amp; Sci, Dept Chem, TR-80000 Osmaniye, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Iminophosphine Palladium Catalysts For Suzuki Carbonylative Coupling Reaction</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/33829</alternateIdentifier>
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  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/aoc.4002</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Three iminophosphine ligands having soft phosphorus and hard nitrogen atoms and their Pd(II) complexes were synthesized and characterized using H-1 NMR, C-13 NMR, P-31 NMR and Fourier transform infrared spectroscopic techniques. Also, electrochemical properties of the iminophosphines and their Pd(II) complexes were investigated in acetonitrile-tetrabutylammonium perchlorate solution with cyclic and square wave voltammetry techniques. All Pd(II) complexes were evaluated as catalysts for carbonylative cross-coupling reactions of aryl iodides with phenylboronic acid. The Suzuki carbonylation of aryl iodides at 80 degrees C under balloon pressure of carbon monoxide in the presence of K2CO3 as a base was examined, and good to high conversions and excellent selectivities were obtained.</description>
  </descriptions>
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