1 Ocak 2018 Dergi makalesi Açık Erişim

Yilmaz, Mustafa Kemal; Keles, Huelya; Ince, Simay; Keles, Mustafa

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  "@id": 33829, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Mersin Univ, Fac Arts & Sci, Dept Chem, TR-33343 Mersin, Turkey", 
      "name": "Yilmaz, Mustafa Kemal"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey", 
      "name": "Keles, Huelya"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey", 
      "name": "Ince, Simay"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey", 
      "name": "Keles, Mustafa"
    }
  ], 
  "datePublished": "2018-01-01", 
  "description": "Three iminophosphine ligands having soft phosphorus and hard nitrogen atoms and their Pd(II) complexes were synthesized and characterized using H-1 NMR, C-13 NMR, P-31 NMR and Fourier transform infrared spectroscopic techniques. Also, electrochemical properties of the iminophosphines and their Pd(II) complexes were investigated in acetonitrile-tetrabutylammonium perchlorate solution with cyclic and square wave voltammetry techniques. All Pd(II) complexes were evaluated as catalysts for carbonylative cross-coupling reactions of aryl iodides with phenylboronic acid. The Suzuki carbonylation of aryl iodides at 80 degrees C under balloon pressure of carbon monoxide in the presence of K2CO3 as a base was examined, and good to high conversions and excellent selectivities were obtained.", 
  "headline": "Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction", 
  "identifier": 33829, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction", 
  "url": "https://aperta.ulakbim.gov.tr/record/33829"
}