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Iminophosphine palladium catalysts for Suzuki carbonylative coupling reaction

Yilmaz, Mustafa Kemal; Keles, Huelya; Ince, Simay; Keles, Mustafa


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        "affiliation": "Mersin Univ, Fac Arts & Sci, Dept Chem, TR-33343 Mersin, Turkey", 
        "name": "Yilmaz, Mustafa Kemal"
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      {
        "affiliation": "Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey", 
        "name": "Keles, Huelya"
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      {
        "affiliation": "Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey", 
        "name": "Ince, Simay"
      }, 
      {
        "affiliation": "Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey", 
        "name": "Keles, Mustafa"
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    "description": "Three iminophosphine ligands having soft phosphorus and hard nitrogen atoms and their Pd(II) complexes were synthesized and characterized using H-1 NMR, C-13 NMR, P-31 NMR and Fourier transform infrared spectroscopic techniques. Also, electrochemical properties of the iminophosphines and their Pd(II) complexes were investigated in acetonitrile-tetrabutylammonium perchlorate solution with cyclic and square wave voltammetry techniques. All Pd(II) complexes were evaluated as catalysts for carbonylative cross-coupling reactions of aryl iodides with phenylboronic acid. The Suzuki carbonylation of aryl iodides at 80 degrees C under balloon pressure of carbon monoxide in the presence of K2CO3 as a base was examined, and good to high conversions and excellent selectivities were obtained.", 
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      "title": "APPLIED ORGANOMETALLIC CHEMISTRY", 
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