1 Ocak 2020 Dergi makalesi Açık Erişim

Turksoy, Abdurrahman; Yildiz, Deniz; Aydonat, Simay; Beduk, Tutku; Canyurt, Merve; Baytekin, Bilge; Akkaya, Engin U.

MARC21 XML

<?xml version='1.0' encoding='UTF-8'?>
<record xmlns="http://www.loc.gov/MARC21/slim">
  <leader>00000nam##2200000uu#4500</leader>
  <datafield tag="909" ind1="C" ind2="O">
    <subfield code="p">user-tubitak-destekli-proje-yayinlari</subfield>
    <subfield code="o">oai:zenodo.org:2891</subfield>
  </datafield>
  <datafield tag="520" ind1=" " ind2=" ">
    <subfield code="a">Controlled generation of singlet oxygen is very important due to its involvement in scheduled cellular maintenance processes and therapeutic potential. As a consequence, precise manipulation of singlet oxygen release rates under mild conditions, is crucial. In this work, a cross-linked polyacrylate, and a polydimethylsiloxane elastomer incorporating anthracene-endoperoxide modules with chain extensions at the 9,10-positions were synthesized. We now report that on mechanical agitation in cryogenic ball mill, fluorescence emission due to anthracene units in the PMA (polymethacrylate) polymer is enhanced, with a concomitant generation of singlet oxygen as proved by detection with a selective probe. The PDMS (polydimethylsiloxane) elastomer with the anthracene endoperoxide mechanophore, is also similarly sensitive to mechanical force.</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">publication</subfield>
    <subfield code="b">article</subfield>
  </datafield>
  <datafield tag="540" ind1=" " ind2=" ">
    <subfield code="a">Creative Commons Attribution</subfield>
    <subfield code="u">http://www.opendefinition.org/licenses/cc-by</subfield>
  </datafield>
  <datafield tag="100" ind1=" " ind2=" ">
    <subfield code="a">Turksoy, Abdurrahman</subfield>
    <subfield code="u">Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="z">md5:0711579da236e600e2c015dfff484ab1</subfield>
    <subfield code="s">174</subfield>
    <subfield code="u">https://aperta.ulakbim.gov.trrecord/2891/files/bib-5d9df171-c7a1-49e6-91fb-d457b5ecd3d9.txt</subfield>
  </datafield>
  <controlfield tag="005">20210315053831.0</controlfield>
  <datafield tag="260" ind1=" " ind2=" ">
    <subfield code="c">2020-01-01</subfield>
  </datafield>
  <datafield tag="024" ind1=" " ind2=" ">
    <subfield code="a">10.1039/d0ra00831a</subfield>
    <subfield code="2">doi</subfield>
  </datafield>
  <datafield tag="542" ind1=" " ind2=" ">
    <subfield code="l">open</subfield>
  </datafield>
  <datafield tag="245" ind1=" " ind2=" ">
    <subfield code="a">Mechanochemical generation of singlet oxygen</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="4">
    <subfield code="v">10</subfield>
    <subfield code="p">RSC ADVANCES</subfield>
    <subfield code="c">9182-9186</subfield>
    <subfield code="n">16</subfield>
  </datafield>
  <datafield tag="650" ind1="1" ind2="7">
    <subfield code="a">cc-by</subfield>
    <subfield code="2">opendefinition.org</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Yildiz, Deniz</subfield>
    <subfield code="u">Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Aydonat, Simay</subfield>
    <subfield code="u">Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Beduk, Tutku</subfield>
    <subfield code="u">Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Canyurt, Merve</subfield>
    <subfield code="u">Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Baytekin, Bilge</subfield>
    <subfield code="u">Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Akkaya, Engin U.</subfield>
    <subfield code="u">Dalian Univ Technol, Dept Pharm, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China</subfield>
  </datafield>
  <controlfield tag="001">2891</controlfield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">user-tubitak-destekli-proje-yayinlari</subfield>
  </datafield>
</record>