1 Ocak 2020 Dergi makalesi Açık Erişim

Turksoy, Abdurrahman; Yildiz, Deniz; Aydonat, Simay; Beduk, Tutku; Canyurt, Merve; Baytekin, Bilge; Akkaya, Engin U.

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        "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Turksoy, Abdurrahman"
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      {
        "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Yildiz, Deniz"
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      {
        "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Aydonat, Simay"
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      {
        "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Beduk, Tutku"
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        "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Canyurt, Merve"
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      {
        "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Baytekin, Bilge"
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      {
        "affiliation": "Dalian Univ Technol, Dept Pharm, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China", 
        "name": "Akkaya, Engin U."
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    "description": "Controlled generation of singlet oxygen is very important due to its involvement in scheduled cellular maintenance processes and therapeutic potential. As a consequence, precise manipulation of singlet oxygen release rates under mild conditions, is crucial. In this work, a cross-linked polyacrylate, and a polydimethylsiloxane elastomer incorporating anthracene-endoperoxide modules with chain extensions at the 9,10-positions were synthesized. We now report that on mechanical agitation in cryogenic ball mill, fluorescence emission due to anthracene units in the PMA (polymethacrylate) polymer is enhanced, with a concomitant generation of singlet oxygen as proved by detection with a selective probe. The PDMS (polydimethylsiloxane) elastomer with the anthracene endoperoxide mechanophore, is also similarly sensitive to mechanical force.", 
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      "pages": "9182-9186", 
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    "title": "Mechanochemical generation of singlet oxygen"
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