1 Ocak 2020 Dergi makalesi Açık Erişim

Turksoy, Abdurrahman; Yildiz, Deniz; Aydonat, Simay; Beduk, Tutku; Canyurt, Merve; Baytekin, Bilge; Akkaya, Engin U.

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  <dc:creator>Turksoy, Abdurrahman</dc:creator>
  <dc:creator>Yildiz, Deniz</dc:creator>
  <dc:creator>Aydonat, Simay</dc:creator>
  <dc:creator>Beduk, Tutku</dc:creator>
  <dc:creator>Canyurt, Merve</dc:creator>
  <dc:creator>Baytekin, Bilge</dc:creator>
  <dc:creator>Akkaya, Engin U.</dc:creator>
  <dc:date>2020-01-01</dc:date>
  <dc:description>Controlled generation of singlet oxygen is very important due to its involvement in scheduled cellular maintenance processes and therapeutic potential. As a consequence, precise manipulation of singlet oxygen release rates under mild conditions, is crucial. In this work, a cross-linked polyacrylate, and a polydimethylsiloxane elastomer incorporating anthracene-endoperoxide modules with chain extensions at the 9,10-positions were synthesized. We now report that on mechanical agitation in cryogenic ball mill, fluorescence emission due to anthracene units in the PMA (polymethacrylate) polymer is enhanced, with a concomitant generation of singlet oxygen as proved by detection with a selective probe. The PDMS (polydimethylsiloxane) elastomer with the anthracene endoperoxide mechanophore, is also similarly sensitive to mechanical force.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/2891</dc:identifier>
  <dc:identifier>oai:zenodo.org:2891</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>RSC ADVANCES 10(16) 9182-9186</dc:source>
  <dc:title>Mechanochemical generation of singlet oxygen</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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