1 Ocak 2020 Dergi makalesi Açık Erişim

Turksoy, Abdurrahman; Yildiz, Deniz; Aydonat, Simay; Beduk, Tutku; Canyurt, Merve; Baytekin, Bilge; Akkaya, Engin U.

Citation Style Language JSON

{
  "DOI": "10.1039/d0ra00831a", 
  "abstract": "Controlled generation of singlet oxygen is very important due to its involvement in scheduled cellular maintenance processes and therapeutic potential. As a consequence, precise manipulation of singlet oxygen release rates under mild conditions, is crucial. In this work, a cross-linked polyacrylate, and a polydimethylsiloxane elastomer incorporating anthracene-endoperoxide modules with chain extensions at the 9,10-positions were synthesized. We now report that on mechanical agitation in cryogenic ball mill, fluorescence emission due to anthracene units in the PMA (polymethacrylate) polymer is enhanced, with a concomitant generation of singlet oxygen as proved by detection with a selective probe. The PDMS (polydimethylsiloxane) elastomer with the anthracene endoperoxide mechanophore, is also similarly sensitive to mechanical force.", 
  "author": [
    {
      "family": "Turksoy", 
      "given": " Abdurrahman"
    }, 
    {
      "family": "Yildiz", 
      "given": " Deniz"
    }, 
    {
      "family": "Aydonat", 
      "given": " Simay"
    }, 
    {
      "family": "Beduk", 
      "given": " Tutku"
    }, 
    {
      "family": "Canyurt", 
      "given": " Merve"
    }, 
    {
      "family": "Baytekin", 
      "given": " Bilge"
    }, 
    {
      "family": "Akkaya", 
      "given": " Engin U."
    }
  ], 
  "container_title": "RSC ADVANCES", 
  "id": "2891", 
  "issue": "16", 
  "issued": {
    "date-parts": [
      [
        2020, 
        1, 
        1
      ]
    ]
  }, 
  "page": "9182-9186", 
  "title": "Mechanochemical generation of singlet oxygen", 
  "type": "article-journal", 
  "volume": "10"
}