1 Ocak 2020 Dergi makalesi Açık Erişim

Turksoy, Abdurrahman; Yildiz, Deniz; Aydonat, Simay; Beduk, Tutku; Canyurt, Merve; Baytekin, Bilge; Akkaya, Engin U.

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{
  "@context": "https://schema.org/", 
  "@id": 2891, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Turksoy, Abdurrahman"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Yildiz, Deniz"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Aydonat, Simay"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Beduk, Tutku"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Canyurt, Merve"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Baytekin, Bilge"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Dalian Univ Technol, Dept Pharm, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China", 
      "name": "Akkaya, Engin U."
    }
  ], 
  "datePublished": "2020-01-01", 
  "description": "Controlled generation of singlet oxygen is very important due to its involvement in scheduled cellular maintenance processes and therapeutic potential. As a consequence, precise manipulation of singlet oxygen release rates under mild conditions, is crucial. In this work, a cross-linked polyacrylate, and a polydimethylsiloxane elastomer incorporating anthracene-endoperoxide modules with chain extensions at the 9,10-positions were synthesized. We now report that on mechanical agitation in cryogenic ball mill, fluorescence emission due to anthracene units in the PMA (polymethacrylate) polymer is enhanced, with a concomitant generation of singlet oxygen as proved by detection with a selective probe. The PDMS (polydimethylsiloxane) elastomer with the anthracene endoperoxide mechanophore, is also similarly sensitive to mechanical force.", 
  "headline": "Mechanochemical generation of singlet oxygen", 
  "identifier": 2891, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Mechanochemical generation of singlet oxygen", 
  "url": "https://aperta.ulakbim.gov.tr/record/2891"
}