1 Ocak 2010 Dergi makalesi Açık Erişim

Demir, Ayhan S.; Talpur, Farah N.

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    <subfield code="a">An efficient chemoenzymatic method for preparing conjugated linoleic acid (CLA) using free linoleic acid (LA) as a substrate is described. In the first step, LA was transformed into 10-hydroxy-cis-12-octadecenoic acid (HA) by the whole cells of Lactobacillus plantarum after 48 h of incubation. The preincubation of whole cells with 0.03% LA resulted in a better yield of HA (480 mg/g) compared to cells grown without LA. In a second fast microwave step, HA was converted to cis-9, trans-11-octadecadienoic acid in the presence of iodine as a catalyst over a silica gel surface. The advantage of this method in preparing cis-9,trans-11 CLA is simple via the whole cell bioconversion of LA into HA via L. plantarum followed by the fast microwave-assisted synthesis of cis-9,trans-11 CLA in higher yields.</subfield>
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    <subfield code="a">Demir, Ayhan S.</subfield>
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    <subfield code="a">Chemoenzymatic Conversion of Linoleic Acid into Conjugated Linoleic Acid</subfield>
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