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Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

Topal, S.; Isci, R.; Sezer, E.; Ozturk, T.; Ustamehmetoglu, B.


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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Topal, S.</dc:creator>
  <dc:creator>Isci, R.</dc:creator>
  <dc:creator>Sezer, E.</dc:creator>
  <dc:creator>Ozturk, T.</dc:creator>
  <dc:creator>Ustamehmetoglu, B.</dc:creator>
  <dc:date>2021-01-01</dc:date>
  <dc:description>Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH(3)OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH(3)OPhTTTPA] and P[CNPhTTTPA] were obtained, respec-tively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spec-troscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong elec-tron withdrawing-CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character. (C) 2021 Published by Elsevier Ltd.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/229688</dc:identifier>
  <dc:identifier>oai:aperta.ulakbim.gov.tr:229688</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>ELECTROCHIMICA ACTA 389</dc:source>
  <dc:title>Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>
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