Dergi makalesi Açık Erişim

Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

Topal, S.; Isci, R.; Sezer, E.; Ozturk, T.; Ustamehmetoglu, B.


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        "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
        "name": "Topal, S."
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      {
        "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
        "name": "Isci, R."
      }, 
      {
        "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
        "name": "Sezer, E."
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      {
        "name": "Ozturk, T."
      }, 
      {
        "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
        "name": "Ustamehmetoglu, B."
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    "description": "Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH(3)OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH(3)OPhTTTPA] and P[CNPhTTTPA] were obtained, respec-tively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spec-troscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong elec-tron withdrawing-CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character. (C) 2021 Published by Elsevier Ltd.", 
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      "title": "ELECTROCHIMICA ACTA", 
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    "title": "Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers"
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