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Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

Topal, S.; Isci, R.; Sezer, E.; Ozturk, T.; Ustamehmetoglu, B.


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{
  "@context": "https://schema.org/", 
  "@id": 229688, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
      "name": "Topal, S."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
      "name": "Isci, R."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
      "name": "Sezer, E."
    }, 
    {
      "@type": "Person", 
      "name": "Ozturk, T."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, Istanbul, Turkey", 
      "name": "Ustamehmetoglu, B."
    }
  ], 
  "datePublished": "2021-01-01", 
  "description": "Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH(3)OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH(3)OPhTTTPA] and P[CNPhTTTPA] were obtained, respec-tively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spec-troscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong elec-tron withdrawing-CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character. (C) 2021 Published by Elsevier Ltd.", 
  "headline": "Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers", 
  "identifier": 229688, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers", 
  "url": "https://aperta.ulakbim.gov.tr/record/229688"
}
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