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Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

Topal, S.; Isci, R.; Sezer, E.; Ozturk, T.; Ustamehmetoglu, B.


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{
  "DOI": "10.1016/j.electacta.2021.138688", 
  "abstract": "Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH(3)OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH(3)OPhTTTPA] and P[CNPhTTTPA] were obtained, respec-tively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spec-troscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong elec-tron withdrawing-CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character. (C) 2021 Published by Elsevier Ltd.", 
  "author": [
    {
      "family": "Topal", 
      "given": " S."
    }, 
    {
      "family": "Isci", 
      "given": " R."
    }, 
    {
      "family": "Sezer", 
      "given": " E."
    }, 
    {
      "family": "Ozturk", 
      "given": " T."
    }, 
    {
      "family": "Ustamehmetoglu", 
      "given": " B."
    }
  ], 
  "container_title": "ELECTROCHIMICA ACTA", 
  "id": "229688", 
  "issued": {
    "date-parts": [
      [
        2021, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers", 
  "type": "article-journal", 
  "volume": "389"
}
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