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Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

Topal, S.; Isci, R.; Sezer, E.; Ozturk, T.; Ustamehmetoglu, B.


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/229688</identifier>
  <creators>
    <creator>
      <creatorName>Topal, S.</creatorName>
      <givenName>S.</givenName>
      <familyName>Topal</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Isci, R.</creatorName>
      <givenName>R.</givenName>
      <familyName>Isci</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sezer, E.</creatorName>
      <givenName>E.</givenName>
      <familyName>Sezer</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ozturk, T.</creatorName>
      <givenName>T.</givenName>
      <familyName>Ozturk</familyName>
    </creator>
    <creator>
      <creatorName>Ustamehmetoglu, B.</creatorName>
      <givenName>B.</givenName>
      <familyName>Ustamehmetoglu</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Electropolymerization Of 3-Arylthieno[3,2-B]Thiophenes And Triphenylamine Based Comonomers</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2021</publicationYear>
  <dates>
    <date dateType="Issued">2021-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/229688</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.electacta.2021.138688</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH(3)OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH(3)OPhTTTPA] and P[CNPhTTTPA] were obtained, respec-tively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spec-troscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong elec-tron withdrawing-CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character. (C) 2021 Published by Elsevier Ltd.</description>
  </descriptions>
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