1 Ocak 2013 Dergi makalesi Açık Erişim

Goksu, Haydar; Dalmizrak, Digdem; Akbayrak, Serdar; Gultekin, Mehmet Serdar; Ozkar, Saim; Metin, Onder

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/15029</identifier>
  <creators>
    <creator>
      <creatorName>Goksu, Haydar</creatorName>
      <givenName>Haydar</givenName>
      <familyName>Goksu</familyName>
    </creator>
    <creator>
      <creatorName>Dalmizrak, Digdem</creatorName>
      <givenName>Digdem</givenName>
      <familyName>Dalmizrak</familyName>
      <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Akbayrak, Serdar</creatorName>
      <givenName>Serdar</givenName>
      <familyName>Akbayrak</familyName>
      <affiliation>Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gultekin, Mehmet Serdar</creatorName>
      <givenName>Mehmet Serdar</givenName>
      <familyName>Gultekin</familyName>
      <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ozkar, Saim</creatorName>
      <givenName>Saim</givenName>
      <familyName>Ozkar</familyName>
      <affiliation>Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Metin, Onder</creatorName>
      <givenName>Onder</givenName>
      <familyName>Metin</familyName>
      <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>One-Pot Synthesis Of 1,2/3-Triols From The Allylic Hydroperoxides Catalyzed By Zeolite-Confined Osmium(0) Nanoclusters</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/15029</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molcata.2013.06.013</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A facile, efficient and eco-friendly method for the one-pot synthesis of 1,2/3-triols from the allylic hydroperoxides were developed by using zeolite-confined osmium(0) nanoclusters as reusable catalyst and without using any co-oxidant (H2O2, (BuOOH)-Bu-t, NMO, etc.) in water/acetone (v/v = 1/4) mixture at room temperature. In this method, the oxygen atom of the allylic hydroperoxide group was transferred to the double bond of the same molecule via zeolite-confined osmium(0) nanoclusters. The method has been successfully applied to various allylic hydroperoxides and the corresponding 1,2/3-triols were obtained in high chemical yield. Moreover, a plausible mechanism was proposed for the catalytic oxidation of allylic hydroperoxide to the respective 1,2/3-triols in the presence of zeolite-Os-0 catalyst gathering all the results collected by testing a variety of allylic hydroperoxides in the presence of zeolite-Os-0 catalyst. (c) 2013 Elsevier B.V. All rights reserved.</description>
  </descriptions>
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