1 Ocak 2013 Dergi makalesi Açık Erişim

Goksu, Haydar; Dalmizrak, Digdem; Akbayrak, Serdar; Gultekin, Mehmet Serdar; Ozkar, Saim; Metin, Onder

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  "@context": "https://schema.org/", 
  "@id": 15029, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Goksu, Haydar"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey", 
      "name": "Dalmizrak, Digdem"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Akbayrak, Serdar"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey", 
      "name": "Gultekin, Mehmet Serdar"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Ozkar, Saim"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey", 
      "name": "Metin, Onder"
    }
  ], 
  "datePublished": "2013-01-01", 
  "description": "A facile, efficient and eco-friendly method for the one-pot synthesis of 1,2/3-triols from the allylic hydroperoxides were developed by using zeolite-confined osmium(0) nanoclusters as reusable catalyst and without using any co-oxidant (H2O2, (BuOOH)-Bu-t, NMO, etc.) in water/acetone (v/v = 1/4) mixture at room temperature. In this method, the oxygen atom of the allylic hydroperoxide group was transferred to the double bond of the same molecule via zeolite-confined osmium(0) nanoclusters. The method has been successfully applied to various allylic hydroperoxides and the corresponding 1,2/3-triols were obtained in high chemical yield. Moreover, a plausible mechanism was proposed for the catalytic oxidation of allylic hydroperoxide to the respective 1,2/3-triols in the presence of zeolite-Os-0 catalyst gathering all the results collected by testing a variety of allylic hydroperoxides in the presence of zeolite-Os-0 catalyst. (c) 2013 Elsevier B.V. All rights reserved.", 
  "headline": "One-pot synthesis of 1,2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters", 
  "identifier": 15029, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "One-pot synthesis of 1,2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters", 
  "url": "https://aperta.ulakbim.gov.tr/record/15029"
}