1 Ocak 2013 Dergi makalesi Açık Erişim

Goksu, Haydar; Dalmizrak, Digdem; Akbayrak, Serdar; Gultekin, Mehmet Serdar; Ozkar, Saim; Metin, Onder

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        "name": "Goksu, Haydar"
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        "affiliation": "Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey", 
        "name": "Dalmizrak, Digdem"
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      {
        "affiliation": "Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Akbayrak, Serdar"
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      {
        "affiliation": "Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey", 
        "name": "Gultekin, Mehmet Serdar"
      }, 
      {
        "affiliation": "Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Ozkar, Saim"
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      {
        "affiliation": "Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey", 
        "name": "Metin, Onder"
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    "description": "A facile, efficient and eco-friendly method for the one-pot synthesis of 1,2/3-triols from the allylic hydroperoxides were developed by using zeolite-confined osmium(0) nanoclusters as reusable catalyst and without using any co-oxidant (H2O2, (BuOOH)-Bu-t, NMO, etc.) in water/acetone (v/v = 1/4) mixture at room temperature. In this method, the oxygen atom of the allylic hydroperoxide group was transferred to the double bond of the same molecule via zeolite-confined osmium(0) nanoclusters. The method has been successfully applied to various allylic hydroperoxides and the corresponding 1,2/3-triols were obtained in high chemical yield. Moreover, a plausible mechanism was proposed for the catalytic oxidation of allylic hydroperoxide to the respective 1,2/3-triols in the presence of zeolite-Os-0 catalyst gathering all the results collected by testing a variety of allylic hydroperoxides in the presence of zeolite-Os-0 catalyst. (c) 2013 Elsevier B.V. All rights reserved.", 
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      "pages": "142-147", 
      "title": "JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL", 
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