1 Ocak 2013 Dergi makalesi Açık Erişim

Goksu, Haydar; Dalmizrak, Digdem; Akbayrak, Serdar; Gultekin, Mehmet Serdar; Ozkar, Saim; Metin, Onder

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{
  "DOI": "10.1016/j.molcata.2013.06.013", 
  "abstract": "A facile, efficient and eco-friendly method for the one-pot synthesis of 1,2/3-triols from the allylic hydroperoxides were developed by using zeolite-confined osmium(0) nanoclusters as reusable catalyst and without using any co-oxidant (H2O2, (BuOOH)-Bu-t, NMO, etc.) in water/acetone (v/v = 1/4) mixture at room temperature. In this method, the oxygen atom of the allylic hydroperoxide group was transferred to the double bond of the same molecule via zeolite-confined osmium(0) nanoclusters. The method has been successfully applied to various allylic hydroperoxides and the corresponding 1,2/3-triols were obtained in high chemical yield. Moreover, a plausible mechanism was proposed for the catalytic oxidation of allylic hydroperoxide to the respective 1,2/3-triols in the presence of zeolite-Os-0 catalyst gathering all the results collected by testing a variety of allylic hydroperoxides in the presence of zeolite-Os-0 catalyst. (c) 2013 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Goksu", 
      "given": " Haydar"
    }, 
    {
      "family": "Dalmizrak", 
      "given": " Digdem"
    }, 
    {
      "family": "Akbayrak", 
      "given": " Serdar"
    }, 
    {
      "family": "Gultekin", 
      "given": " Mehmet Serdar"
    }, 
    {
      "family": "Ozkar", 
      "given": " Saim"
    }, 
    {
      "family": "Metin", 
      "given": " Onder"
    }
  ], 
  "container_title": "JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL", 
  "id": "15029", 
  "issued": {
    "date-parts": [
      [
        2013, 
        1, 
        1
      ]
    ]
  }, 
  "page": "142-147", 
  "title": "One-pot synthesis of 1,2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters", 
  "type": "article-journal", 
  "volume": "378"
}