Dergi makalesi Açık Erişim
Kip, Cigdem; Erkakan, Damla; Gokaltun, Aslihan; Celebi, Bekir; Tuncel, Ali
<?xml version='1.0' encoding='UTF-8'?> <record xmlns="http://www.loc.gov/MARC21/slim"> <leader>00000nam##2200000uu#4500</leader> <controlfield tag="001">82947</controlfield> <datafield tag="540" ind1=" " ind2=" "> <subfield code="a">Creative Commons Attribution</subfield> <subfield code="u">http://www.opendefinition.org/licenses/cc-by</subfield> </datafield> <datafield tag="909" ind1="C" ind2="4"> <subfield code="v">1396</subfield> <subfield code="p">JOURNAL OF CHROMATOGRAPHY A</subfield> <subfield code="c">86-97</subfield> </datafield> <controlfield tag="005">20210316060801.0</controlfield> <datafield tag="520" ind1=" " ind2=" "> <subfield code="a">Poly(3-chloro-2-hydroxypropyl methacrylate-co-ethylene dimethacrylate), poly(HPMA-Cl-co-EDMA) capillary monolith was proposed as a reactive starting material with tailoring flexibility for the preparation of monolithic stationary phases. The reactive capillary monolith was synthesized by free radical copolymerization of 3-chloro-2-hydroxypropyl methacrylate (HPMA-Cl) and ethylene dimethacrylate (EDMA). The mean pore size, the specific surface area and the permeability of poly(HPMA-Cl-co-EDMA) monoliths were controlled by adjusting porogen/monomer volume ratio, porogen composition and polymerization temperature. The porogen/monomer volume ratio was found as the most effective factor controlling the porous properties of poly(HPMA-Cl-co-EDMA) monolith. Triethanolamine (TEA-OH) functionalized polymethacrylate monoliths were prepared by using the reactive chloropropyl group of poly(HPMA-Cl-co-EDMA) monolith via one-pot and simple post-functionalization process. Poly(HPMA-Cl-co-EDMA) monolith reacted with TEA-OH was evaluated as a stationary phase in nano-hydrophilic interaction chromatography (nano-HILIC). Nucleotides, nucleosides and benzoic acid derivatives were satisfactorily separated with the plate heights up to 20 mu m. TEA-OH attached-poly(HPMA-Cl-co-EDIVIA) monolith showed a reproducible and stable retention behaviour in nano-HILIC runs. However, a decrease in the column performance (i.e. an increase in the plate height) was observed with the increasing retention factor. Hence "retention-dependent column efficiency" behaviour was shown for HILIC mode using the chromatographic data collected with the polymer based monolith synthesized. (C) 2015 Elsevier B.V. All rights reserved.</subfield> </datafield> <datafield tag="245" ind1=" " ind2=" "> <subfield code="a">Synthesis of a reactive polymethacrylate capillary monolith and its use as a starting material for the preparation of a stationary phase for hydrophilic interaction chromatography</subfield> </datafield> <datafield tag="909" ind1="C" ind2="O"> <subfield code="p">user-tubitak-destekli-proje-yayinlari</subfield> <subfield code="o">oai:zenodo.org:82947</subfield> </datafield> <datafield tag="542" ind1=" " ind2=" "> <subfield code="l">open</subfield> </datafield> <datafield tag="100" ind1=" " ind2=" "> <subfield code="u">Hacettepe Univ, Dept Chem Engn, TR-06532 Ankara, Turkey</subfield> <subfield code="a">Kip, Cigdem</subfield> </datafield> <datafield tag="980" ind1=" " ind2=" "> <subfield code="a">user-tubitak-destekli-proje-yayinlari</subfield> </datafield> <datafield tag="856" ind1="4" ind2=" "> <subfield code="z">md5:35be6e01fc3fe5060277f02c5cd65fa4</subfield> <subfield code="s">296</subfield> <subfield code="u">https://aperta.ulakbim.gov.trrecord/82947/files/bib-37a15e8b-7388-4f78-8602-4a1f2cb473a2.txt</subfield> </datafield> <datafield tag="024" ind1=" " ind2=" "> <subfield code="2">doi</subfield> <subfield code="a">10.1016/j.chroma.2015.04.005</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Hacettepe Univ, Dept Chem Engn, TR-06532 Ankara, Turkey</subfield> <subfield code="a">Erkakan, Damla</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Hacettepe Univ, Dept Chem Engn, TR-06532 Ankara, Turkey</subfield> <subfield code="a">Gokaltun, Aslihan</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Hacettepe Univ, Dept Chem Engn, TR-06532 Ankara, Turkey</subfield> <subfield code="a">Celebi, Bekir</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="a">Tuncel, Ali</subfield> </datafield> <datafield tag="650" ind1="1" ind2="7"> <subfield code="a">cc-by</subfield> <subfield code="2">opendefinition.org</subfield> </datafield> <datafield tag="980" ind1=" " ind2=" "> <subfield code="a">publication</subfield> <subfield code="b">article</subfield> </datafield> <datafield tag="260" ind1=" " ind2=" "> <subfield code="c">2015-01-01</subfield> </datafield> </record>
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