Dergi makalesi Açık Erişim
Kazancioglu, Mustafa Zahrittin; Kazancioglu, Elif Akin; Secen, Hasan; Altundas, Ramazan
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"> <dc:creator>Kazancioglu, Mustafa Zahrittin</dc:creator> <dc:creator>Kazancioglu, Elif Akin</dc:creator> <dc:creator>Secen, Hasan</dc:creator> <dc:creator>Altundas, Ramazan</dc:creator> <dc:date>2015-01-01</dc:date> <dc:description>The oxidation reactions of amino and hydroxylamino substituted alkylfurans were explored for the synthesis of structurally complex compounds from simple starting materials. A novel photooxygenation of the furan derivatives gave an alpha,beta-unsaturated dicarbonyl moiety which underwent subsequent conjugate addition to yield diastereomeric mixtures of the corresponding pyrrolidine and isoxazoline heterocycles. Oxidation of the alpha,beta-unsaturated dicarbonyl using mCPBA gave epoxide intermediates, which were opened by nucleophilic attack of the amino groups, furnishing pyrrolidine and isoxazolidine heterocycles. (C) 2015 Elsevier Ltd. All rights reserved.</dc:description> <dc:identifier>https://aperta.ulakbim.gov.trrecord/82287</dc:identifier> <dc:identifier>oai:zenodo.org:82287</dc:identifier> <dc:rights>info:eu-repo/semantics/openAccess</dc:rights> <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights> <dc:source>TETRAHEDRON LETTERS 56(50) 6994-6997</dc:source> <dc:title>Oxidation of aminoalkyl and hydroxylaminoalkyl furans</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> <dc:type>publication-article</dc:type> </oai_dc:dc>
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