Dergi makalesi Açık Erişim
Kazancioglu, Mustafa Zahrittin; Kazancioglu, Elif Akin; Secen, Hasan; Altundas, Ramazan
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/82287</identifier> <creators> <creator> <creatorName>Kazancioglu, Mustafa Zahrittin</creatorName> <givenName>Mustafa Zahrittin</givenName> <familyName>Kazancioglu</familyName> <affiliation>Ataturk Univ, Dept Chem, Coll Sci, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Kazancioglu, Elif Akin</creatorName> <givenName>Elif Akin</givenName> <familyName>Kazancioglu</familyName> <affiliation>Ataturk Univ, Dept Chem, Coll Sci, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Secen, Hasan</creatorName> <givenName>Hasan</givenName> <familyName>Secen</familyName> <affiliation>Ataturk Univ, Dept Chem, Coll Sci, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Altundas, Ramazan</creatorName> <givenName>Ramazan</givenName> <familyName>Altundas</familyName> <affiliation>Ataturk Univ, Dept Chem, Coll Sci, TR-25240 Erzurum, Turkey</affiliation> </creator> </creators> <titles> <title>Oxidation Of Aminoalkyl And Hydroxylaminoalkyl Furans</title> </titles> <publisher>Aperta</publisher> <publicationYear>2015</publicationYear> <dates> <date dateType="Issued">2015-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/82287</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.tetlet.2015.10.105</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">The oxidation reactions of amino and hydroxylamino substituted alkylfurans were explored for the synthesis of structurally complex compounds from simple starting materials. A novel photooxygenation of the furan derivatives gave an alpha,beta-unsaturated dicarbonyl moiety which underwent subsequent conjugate addition to yield diastereomeric mixtures of the corresponding pyrrolidine and isoxazoline heterocycles. Oxidation of the alpha,beta-unsaturated dicarbonyl using mCPBA gave epoxide intermediates, which were opened by nucleophilic attack of the amino groups, furnishing pyrrolidine and isoxazolidine heterocycles. (C) 2015 Elsevier Ltd. All rights reserved.</description> </descriptions> </resource>
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