1 Ocak 2020 Dergi makalesi Açık Erişim

Warner, Caroline C.; Thooft, Andrea M.; Norris, Sean R.; Lampkin, Bryan J.; Demirci, Selin K.; VanVeller, Brett

Dublin Core

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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Warner, Caroline C.</dc:creator>
  <dc:creator>Thooft, Andrea M.</dc:creator>
  <dc:creator>Norris, Sean R.</dc:creator>
  <dc:creator>Lampkin, Bryan J.</dc:creator>
  <dc:creator>Demirci, Selin K.</dc:creator>
  <dc:creator>VanVeller, Brett</dc:creator>
  <dc:date>2020-01-01</dc:date>
  <dc:description>A new design strategy to control the efficiency of a photocleavage reaction based on changing the nature of the excited state is presented. A novel class of photoactive compounds has been synthesized by combining the classicalo-nitrobenzyl scaffold with an environmentally sensitive dye, 4-amino-nitrobenzothiazole. Irradiation in a polar solvent led to an excited state that was inoperative for photochemistry whereas excitation in a nonpolar solvent led to an excited state that was photochemically active. While our design hypothesis tests true for the on/off control of a photochemical process, an alternative photochemical ring-opening of the heterocycle appears to be the preferred process in contrast to the intended photocleavage process.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/8053</dc:identifier>
  <dc:identifier>oai:zenodo.org:8053</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>CHEMISTRYSELECT 5(23) 7016-7020</dc:source>
  <dc:title>The Malleable Excited States of Benzothiadiazole Dyes and Investigation of their Potential for Photochemical Control</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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