1 Ocak 2020 Dergi makalesi Açık Erişim

Warner, Caroline C.; Thooft, Andrea M.; Norris, Sean R.; Lampkin, Bryan J.; Demirci, Selin K.; VanVeller, Brett

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{
  "@context": "https://schema.org/", 
  "@id": 8053, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Iowa State Univ, Dept Chem, Ames, IA 50010 USA", 
      "name": "Warner, Caroline C."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Iowa State Univ, Dept Chem, Ames, IA 50010 USA", 
      "name": "Thooft, Andrea M."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Iowa State Univ, Dept Chem, Ames, IA 50010 USA", 
      "name": "Norris, Sean R."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Iowa State Univ, Dept Chem, Ames, IA 50010 USA", 
      "name": "Lampkin, Bryan J."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Amasya Univ, Dept Chem, Amasya, Turkey", 
      "name": "Demirci, Selin K."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Iowa State Univ, Dept Chem, Ames, IA 50010 USA", 
      "name": "VanVeller, Brett"
    }
  ], 
  "datePublished": "2020-01-01", 
  "description": "A new design strategy to control the efficiency of a photocleavage reaction based on changing the nature of the excited state is presented. A novel class of photoactive compounds has been synthesized by combining the classicalo-nitrobenzyl scaffold with an environmentally sensitive dye, 4-amino-nitrobenzothiazole. Irradiation in a polar solvent led to an excited state that was inoperative for photochemistry whereas excitation in a nonpolar solvent led to an excited state that was photochemically active. While our design hypothesis tests true for the on/off control of a photochemical process, an alternative photochemical ring-opening of the heterocycle appears to be the preferred process in contrast to the intended photocleavage process.", 
  "headline": "The Malleable Excited States of Benzothiadiazole Dyes and Investigation of their Potential for Photochemical Control", 
  "identifier": 8053, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "The Malleable Excited States of Benzothiadiazole Dyes and Investigation of their Potential for Photochemical Control", 
  "url": "https://aperta.ulakbim.gov.tr/record/8053"
}