1 Ocak 2020 Dergi makalesi Açık Erişim

Warner, Caroline C.; Thooft, Andrea M.; Norris, Sean R.; Lampkin, Bryan J.; Demirci, Selin K.; VanVeller, Brett

DataCite XML

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/8053</identifier>
  <creators>
    <creator>
      <creatorName>Warner, Caroline C.</creatorName>
      <givenName>Caroline C.</givenName>
      <familyName>Warner</familyName>
      <affiliation>Iowa State Univ, Dept Chem, Ames, IA 50010 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Thooft, Andrea M.</creatorName>
      <givenName>Andrea M.</givenName>
      <familyName>Thooft</familyName>
      <affiliation>Iowa State Univ, Dept Chem, Ames, IA 50010 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Norris, Sean R.</creatorName>
      <givenName>Sean R.</givenName>
      <familyName>Norris</familyName>
      <affiliation>Iowa State Univ, Dept Chem, Ames, IA 50010 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Lampkin, Bryan J.</creatorName>
      <givenName>Bryan J.</givenName>
      <familyName>Lampkin</familyName>
      <affiliation>Iowa State Univ, Dept Chem, Ames, IA 50010 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Demirci, Selin K.</creatorName>
      <givenName>Selin K.</givenName>
      <familyName>Demirci</familyName>
      <affiliation>Amasya Univ, Dept Chem, Amasya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>VanVeller, Brett</creatorName>
      <givenName>Brett</givenName>
      <familyName>VanVeller</familyName>
      <affiliation>Iowa State Univ, Dept Chem, Ames, IA 50010 USA</affiliation>
    </creator>
  </creators>
  <titles>
    <title>The Malleable Excited States Of Benzothiadiazole Dyes And Investigation Of Their Potential For Photochemical Control</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/8053</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/slct.202001980</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A new design strategy to control the efficiency of a photocleavage reaction based on changing the nature of the excited state is presented. A novel class of photoactive compounds has been synthesized by combining the classicalo-nitrobenzyl scaffold with an environmentally sensitive dye, 4-amino-nitrobenzothiazole. Irradiation in a polar solvent led to an excited state that was inoperative for photochemistry whereas excitation in a nonpolar solvent led to an excited state that was photochemically active. While our design hypothesis tests true for the on/off control of a photochemical process, an alternative photochemical ring-opening of the heterocycle appears to be the preferred process in contrast to the intended photocleavage process.</description>
  </descriptions>
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