1 Ocak 2020 Dergi makalesi Açık Erişim

Warner, Caroline C.; Thooft, Andrea M.; Norris, Sean R.; Lampkin, Bryan J.; Demirci, Selin K.; VanVeller, Brett

Citation Style Language JSON

{
  "DOI": "10.1002/slct.202001980", 
  "abstract": "A new design strategy to control the efficiency of a photocleavage reaction based on changing the nature of the excited state is presented. A novel class of photoactive compounds has been synthesized by combining the classicalo-nitrobenzyl scaffold with an environmentally sensitive dye, 4-amino-nitrobenzothiazole. Irradiation in a polar solvent led to an excited state that was inoperative for photochemistry whereas excitation in a nonpolar solvent led to an excited state that was photochemically active. While our design hypothesis tests true for the on/off control of a photochemical process, an alternative photochemical ring-opening of the heterocycle appears to be the preferred process in contrast to the intended photocleavage process.", 
  "author": [
    {
      "family": "Warner", 
      "given": " Caroline C."
    }, 
    {
      "family": "Thooft", 
      "given": " Andrea M."
    }, 
    {
      "family": "Norris", 
      "given": " Sean R."
    }, 
    {
      "family": "Lampkin", 
      "given": " Bryan J."
    }, 
    {
      "family": "Demirci", 
      "given": " Selin K."
    }, 
    {
      "family": "VanVeller", 
      "given": " Brett"
    }
  ], 
  "container_title": "CHEMISTRYSELECT", 
  "id": "8053", 
  "issue": "23", 
  "issued": {
    "date-parts": [
      [
        2020, 
        1, 
        1
      ]
    ]
  }, 
  "page": "7016-7020", 
  "title": "The Malleable Excited States of Benzothiadiazole Dyes and Investigation of their Potential for Photochemical Control", 
  "type": "article-journal", 
  "volume": "5"
}