Dergi makalesi Açık Erişim
Sendil, Kivilcim; Keskin, Selbi; Balci, Metin
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"> <dc:creator>Sendil, Kivilcim</dc:creator> <dc:creator>Keskin, Selbi</dc:creator> <dc:creator>Balci, Metin</dc:creator> <dc:date>2019-01-01</dc:date> <dc:description>A concise and regioselective approach to the synthesis of pyridine-fused heterocycles and benzoxazepine derivatives was developed. Propargyl imines derived from aromatic aldehydes and propargyl amine underwent 6 pi-electrocyclization reactions at high temperatures in high yields to form pyridine-fused heterocycles. Application of the same methodology to aromatic imines having a hydroxyl group in the ortho position resulted in the formation of (benz)oxazepine derivatives. The formation mechanism of the products was discussed. (C) 2019 Elsevier Ltd. All rights reserved.</dc:description> <dc:identifier>https://aperta.ulakbim.gov.trrecord/74961</dc:identifier> <dc:identifier>oai:zenodo.org:74961</dc:identifier> <dc:rights>info:eu-repo/semantics/openAccess</dc:rights> <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights> <dc:source>TETRAHEDRON 75(46)</dc:source> <dc:title>Concise design and synthesis of pyridine-fused heterocycles via 6 pi- Azaelectrocyclization process of iminoalkyne derivatives</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> <dc:type>publication-article</dc:type> </oai_dc:dc>
Görüntülenme | 28 |
İndirme | 4 |
Veri hacmi | 764 Bytes |
Tekil görüntülenme | 27 |
Tekil indirme | 4 |