Dergi makalesi Açık Erişim
Sendil, Kivilcim; Keskin, Selbi; Balci, Metin
{ "@context": "https://schema.org/", "@id": 74961, "@type": "ScholarlyArticle", "creator": [ { "@type": "Person", "name": "Sendil, Kivilcim" }, { "@type": "Person", "name": "Keskin, Selbi" }, { "@type": "Person", "affiliation": "Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey", "name": "Balci, Metin" } ], "datePublished": "2019-01-01", "description": "A concise and regioselective approach to the synthesis of pyridine-fused heterocycles and benzoxazepine derivatives was developed. Propargyl imines derived from aromatic aldehydes and propargyl amine underwent 6 pi-electrocyclization reactions at high temperatures in high yields to form pyridine-fused heterocycles. Application of the same methodology to aromatic imines having a hydroxyl group in the ortho position resulted in the formation of (benz)oxazepine derivatives. The formation mechanism of the products was discussed. (C) 2019 Elsevier Ltd. All rights reserved.", "headline": "Concise design and synthesis of pyridine-fused heterocycles via 6 pi- Azaelectrocyclization process of iminoalkyne derivatives", "identifier": 74961, "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", "license": "http://www.opendefinition.org/licenses/cc-by", "name": "Concise design and synthesis of pyridine-fused heterocycles via 6 pi- Azaelectrocyclization process of iminoalkyne derivatives", "url": "https://aperta.ulakbim.gov.tr/record/74961" }
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