1 Ocak 2019 Dergi makalesi Açık Erişim

Sendil, Kivilcim; Keskin, Selbi; Balci, Metin

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/74961</identifier>
  <creators>
    <creator>
      <creatorName>Sendil, Kivilcim</creatorName>
      <givenName>Kivilcim</givenName>
      <familyName>Sendil</familyName>
    </creator>
    <creator>
      <creatorName>Keskin, Selbi</creatorName>
      <givenName>Selbi</givenName>
      <familyName>Keskin</familyName>
    </creator>
    <creator>
      <creatorName>Balci, Metin</creatorName>
      <givenName>Metin</givenName>
      <familyName>Balci</familyName>
      <affiliation>Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Concise Design And Synthesis Of Pyridine-Fused Heterocycles Via 6 Pi- Azaelectrocyclization Process Of Iminoalkyne Derivatives</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2019</publicationYear>
  <dates>
    <date dateType="Issued">2019-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/74961</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.tet.2019.130660</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
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  <descriptions>
    <description descriptionType="Abstract">A concise and regioselective approach to the synthesis of pyridine-fused heterocycles and benzoxazepine derivatives was developed. Propargyl imines derived from aromatic aldehydes and propargyl amine underwent 6 pi-electrocyclization reactions at high temperatures in high yields to form pyridine-fused heterocycles. Application of the same methodology to aromatic imines having a hydroxyl group in the ortho position resulted in the formation of (benz)oxazepine derivatives. The formation mechanism of the products was discussed. (C) 2019 Elsevier Ltd. All rights reserved.</description>
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