Dergi makalesi Açık Erişim

Rapid Analysis of Polycyclic Aromatic Hydrocarbons in Water Samples Using an Automated On-line Two-Dimensional Liquid Chromatography

Armutcu, Canan; Ozgur, Erdogan; Karasu, Tunca; Bayram, Engin; Uzun, Lokman; Corman, Mehmet Emin


JSON

{
  "conceptrecid": "67468", 
  "created": "2021-03-16T02:35:28.815554+00:00", 
  "doi": "10.1007/s11270-019-4306-7", 
  "files": [
    {
      "bucket": "035f6309-5a14-452d-a486-f90018900f6e", 
      "checksum": "md5:9ada0091ba594133a57231c29821adca", 
      "key": "bib-74de842f-3c86-458b-85bf-c0fad6e344e4.txt", 
      "links": {
        "self": "https://aperta.ulakbim.gov.tr/api/files/035f6309-5a14-452d-a486-f90018900f6e/bib-74de842f-3c86-458b-85bf-c0fad6e344e4.txt"
      }, 
      "size": 250, 
      "type": "txt"
    }
  ], 
  "id": 67469, 
  "links": {
    "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1007/s11270-019-4306-7.svg", 
    "bucket": "https://aperta.ulakbim.gov.tr/api/files/035f6309-5a14-452d-a486-f90018900f6e", 
    "doi": "https://doi.org/10.1007/s11270-019-4306-7", 
    "html": "https://aperta.ulakbim.gov.tr/record/67469", 
    "latest": "https://aperta.ulakbim.gov.tr/api/records/67469", 
    "latest_html": "https://aperta.ulakbim.gov.tr/record/67469"
  }, 
  "metadata": {
    "access_right": "open", 
    "access_right_category": "success", 
    "communities": [
      {
        "id": "tubitak-destekli-proje-yayinlari"
      }
    ], 
    "creators": [
      {
        "affiliation": "Hacettepe Univ, Dept Chem, Fac Sci, Ankara, Turkey", 
        "name": "Armutcu, Canan"
      }, 
      {
        "name": "Ozgur, Erdogan"
      }, 
      {
        "affiliation": "Sinop Univ, Dept Chem, Fac Sci & Arts, Sinop, Turkey", 
        "name": "Karasu, Tunca"
      }, 
      {
        "affiliation": "Hacettepe Univ, Dept Chem, Fac Sci, Ankara, Turkey", 
        "name": "Bayram, Engin"
      }, 
      {
        "name": "Uzun, Lokman"
      }, 
      {
        "affiliation": "Sinop Univ, Dept Chem, Fac Sci & Arts, Sinop, Turkey", 
        "name": "Corman, Mehmet Emin"
      }
    ], 
    "description": "Two-dimensional HPLC (2D-HPLC) recently has received great attention due to providing high resolving power and higher peak capacities than that of 1D-HPLC, especially dealing with a wide spectrum of sample matrices containing several components. In this work, an on-line heart-cutting two-dimensional liquid chromatography (2D-LC) method was developed using monolithic columns coupled with reversed-phase liquid chromatography (RPLC). 2D-HPLC was successfully carried out using affinity-based monolithic columns at first dimension (20 cm x 4.6 mm I.D.) followed by a Pinnacle II PAH column (50 mm x 4.6 mm I.D.) at the second dimension. Furthermore, good linearity was observed for the correlation of the benzo[a]pyrene (BaP) molecule against the peak areas (R-2 = 0.994) in the concentration range of 0.01-1.0 ng/mL in 30 min. The limit of detection and the limit of quantification were found to be 4.0 pg/mL and 12.0 pg/mL, respectively. Both the intra-day and inter-day precision at 0.01 and 0.1 ng/mL spiked concentrations were below than 2.35% RSD whereas the means of the recovery data of the BaP from the water samples were found to be in the range of 93.71-98.65%. These results demonstrate that the 2D-HPLC system, developed by the combination of the P(HEMA-MAPA) column and Pinnacle II PAH column, is reliable, stable, and well qualified in the extraction of polycyclic aromatic hydrocarbons from the water samples.", 
    "doi": "10.1007/s11270-019-4306-7", 
    "has_grant": false, 
    "journal": {
      "issue": "10", 
      "title": "WATER AIR AND SOIL POLLUTION", 
      "volume": "230"
    }, 
    "license": {
      "id": "cc-by"
    }, 
    "publication_date": "2019-01-01", 
    "relations": {
      "version": [
        {
          "count": 1, 
          "index": 0, 
          "is_last": true, 
          "last_child": {
            "pid_type": "recid", 
            "pid_value": "67469"
          }, 
          "parent": {
            "pid_type": "recid", 
            "pid_value": "67468"
          }
        }
      ]
    }, 
    "resource_type": {
      "subtype": "article", 
      "title": "Dergi makalesi", 
      "type": "publication"
    }, 
    "title": "Rapid Analysis of Polycyclic Aromatic Hydrocarbons in Water Samples Using an Automated On-line Two-Dimensional Liquid Chromatography"
  }, 
  "owners": [
    1
  ], 
  "revision": 1, 
  "stats": {
    "downloads": 6.0, 
    "unique_downloads": 6.0, 
    "unique_views": 30.0, 
    "version_downloads": 6.0, 
    "version_unique_downloads": 6.0, 
    "version_unique_views": 30.0, 
    "version_views": 32.0, 
    "version_volume": 1500.0, 
    "views": 32.0, 
    "volume": 1500.0
  }, 
  "updated": "2021-03-16T02:35:28.877750+00:00"
}
32
6
görüntülenme
indirilme
Görüntülenme 32
İndirme 6
Veri hacmi 1.5 kB
Tekil görüntülenme 30
Tekil indirme 6

Alıntı yap