1 Ocak 2019 Dergi makalesi Açık Erişim

Armutcu, Canan; Ozgur, Erdogan; Karasu, Tunca; Bayram, Engin; Uzun, Lokman; Corman, Mehmet Emin

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{
  "DOI": "10.1007/s11270-019-4306-7", 
  "abstract": "Two-dimensional HPLC (2D-HPLC) recently has received great attention due to providing high resolving power and higher peak capacities than that of 1D-HPLC, especially dealing with a wide spectrum of sample matrices containing several components. In this work, an on-line heart-cutting two-dimensional liquid chromatography (2D-LC) method was developed using monolithic columns coupled with reversed-phase liquid chromatography (RPLC). 2D-HPLC was successfully carried out using affinity-based monolithic columns at first dimension (20 cm x 4.6 mm I.D.) followed by a Pinnacle II PAH column (50 mm x 4.6 mm I.D.) at the second dimension. Furthermore, good linearity was observed for the correlation of the benzo[a]pyrene (BaP) molecule against the peak areas (R-2 = 0.994) in the concentration range of 0.01-1.0 ng/mL in 30 min. The limit of detection and the limit of quantification were found to be 4.0 pg/mL and 12.0 pg/mL, respectively. Both the intra-day and inter-day precision at 0.01 and 0.1 ng/mL spiked concentrations were below than 2.35% RSD whereas the means of the recovery data of the BaP from the water samples were found to be in the range of 93.71-98.65%. These results demonstrate that the 2D-HPLC system, developed by the combination of the P(HEMA-MAPA) column and Pinnacle II PAH column, is reliable, stable, and well qualified in the extraction of polycyclic aromatic hydrocarbons from the water samples.", 
  "author": [
    {
      "family": "Armutcu", 
      "given": " Canan"
    }, 
    {
      "family": "Ozgur", 
      "given": " Erdogan"
    }, 
    {
      "family": "Karasu", 
      "given": " Tunca"
    }, 
    {
      "family": "Bayram", 
      "given": " Engin"
    }, 
    {
      "family": "Uzun", 
      "given": " Lokman"
    }, 
    {
      "family": "Corman", 
      "given": " Mehmet Emin"
    }
  ], 
  "container_title": "WATER AIR AND SOIL POLLUTION", 
  "id": "67469", 
  "issue": "10", 
  "issued": {
    "date-parts": [
      [
        2019, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Rapid Analysis of Polycyclic Aromatic Hydrocarbons in Water Samples Using an Automated On-line Two-Dimensional Liquid Chromatography", 
  "type": "article-journal", 
  "volume": "230"
}