1 Ocak 2014 Dergi makalesi Açık Erişim

Kalay, Erbay; Kilic, Hamdullah; Catir, Mustafa; Cakici, Murat; Kazaz, Cavit

Dublin Core

<?xml version='1.0' encoding='utf-8'?>
<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Kalay, Erbay</dc:creator>
  <dc:creator>Kilic, Hamdullah</dc:creator>
  <dc:creator>Catir, Mustafa</dc:creator>
  <dc:creator>Cakici, Murat</dc:creator>
  <dc:creator>Kazaz, Cavit</dc:creator>
  <dc:date>2014-01-01</dc:date>
  <dc:description>A novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (O-1(2)) under biphasic conditions. The existence of O-1(2) was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of O-1(2) production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/64515</dc:identifier>
  <dc:identifier>oai:zenodo.org:64515</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>PURE AND APPLIED CHEMISTRY 86(6) 945-952</dc:source>
  <dc:title>Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>