1 Ocak 2014 Dergi makalesi Açık Erişim

Kalay, Erbay; Kilic, Hamdullah; Catir, Mustafa; Cakici, Murat; Kazaz, Cavit

Citation Style Language JSON

{
  "DOI": "10.1515/pac-2013-0812", 
  "abstract": "A novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (O-1(2)) under biphasic conditions. The existence of O-1(2) was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of O-1(2) production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.", 
  "author": [
    {
      "family": "Kalay", 
      "given": " Erbay"
    }, 
    {
      "family": "Kilic", 
      "given": " Hamdullah"
    }, 
    {
      "family": "Catir", 
      "given": " Mustafa"
    }, 
    {
      "family": "Cakici", 
      "given": " Murat"
    }, 
    {
      "family": "Kazaz", 
      "given": " Cavit"
    }
  ], 
  "container_title": "PURE AND APPLIED CHEMISTRY", 
  "id": "64515", 
  "issue": "6", 
  "issued": {
    "date-parts": [
      [
        2014, 
        1, 
        1
      ]
    ]
  }, 
  "page": "945-952", 
  "title": "Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents", 
  "type": "article-journal", 
  "volume": "86"
}