1 Ocak 2014 Dergi makalesi Açık Erişim

Kalay, Erbay; Kilic, Hamdullah; Catir, Mustafa; Cakici, Murat; Kazaz, Cavit

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/64515</identifier>
  <creators>
    <creator>
      <creatorName>Kalay, Erbay</creatorName>
      <givenName>Erbay</givenName>
      <familyName>Kalay</familyName>
      <affiliation>Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kilic, Hamdullah</creatorName>
      <givenName>Hamdullah</givenName>
      <familyName>Kilic</familyName>
      <affiliation>Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Catir, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Catir</familyName>
      <affiliation>Erzincan Univ, Fac Arts &amp; Sci, Dept Chem, TR-24100 Erzincan, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Cakici, Murat</creatorName>
      <givenName>Murat</givenName>
      <familyName>Cakici</familyName>
      <affiliation>Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kazaz, Cavit</creatorName>
      <givenName>Cavit</givenName>
      <familyName>Kazaz</familyName>
      <affiliation>Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Generation Of Singlet Oxygen (O-1(2)) From Hydrogen Peroxide Decomposition By In Situ Generated Hypervalent Iodoarene Reagents</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2014</publicationYear>
  <dates>
    <date dateType="Issued">2014-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/64515</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1515/pac-2013-0812</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (O-1(2)) under biphasic conditions. The existence of O-1(2) was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of O-1(2) production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.</description>
  </descriptions>
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